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Pressure
- Jan 15, 2019 -

For condensed phases (solids and liquids), the pressure dependence of solubility is typically weak and usually neglected in practice.

where the index i iterates the components, Ni is the mole fraction of the ith component in the solution, P is the pressure, the index T refers to constant temperature, Vi,aq is the partial molar volume of the ithcomponent in the solution, Vi,cr is the partial molar volume of the ith component in the dissolving solid, and R is the universal gas constant.

The pressure dependence of solubility does occasionally have practical significance. For example, precipitation fouling of oil fields and wells by calcium sulfate (which decreases its solubility with decreasing pressure) can result in decreased productivity with time.


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